ISSN   1004-0595

CN  62-1224/O4

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王东胜, 强强, 夏呈祥, 朱奋永, 孙士斌, 常雪婷. FH36钢在不同盐度模拟海水中的摩擦腐蚀行为研究[J]. 摩擦学学报, 2023, 43(1): 64-72. DOI: 10.16078/j.tribology.2021270
引用本文: 王东胜, 强强, 夏呈祥, 朱奋永, 孙士斌, 常雪婷. FH36钢在不同盐度模拟海水中的摩擦腐蚀行为研究[J]. 摩擦学学报, 2023, 43(1): 64-72. DOI: 10.16078/j.tribology.2021270
WANG Dongsheng, QIANG Qiang, XIA Chengxiang, ZHU Fenyong, SUN Shibin, CHANG Xueting. Tribocorrosion Behavior of FH36 Steel in Simulated Seawater with Different Salinity[J]. TRIBOLOGY, 2023, 43(1): 64-72. DOI: 10.16078/j.tribology.2021270
Citation: WANG Dongsheng, QIANG Qiang, XIA Chengxiang, ZHU Fenyong, SUN Shibin, CHANG Xueting. Tribocorrosion Behavior of FH36 Steel in Simulated Seawater with Different Salinity[J]. TRIBOLOGY, 2023, 43(1): 64-72. DOI: 10.16078/j.tribology.2021270

FH36钢在不同盐度模拟海水中的摩擦腐蚀行为研究

Tribocorrosion Behavior of FH36 Steel in Simulated Seawater with Different Salinity

  • 摘要: 本文中利用UMT-2型多功能摩擦磨损实验机,分别测试FH36船用低温钢板在不同盐度模拟海水中摩擦腐蚀行为. 结合电化学工作站监测FH36钢样在摩擦腐蚀过程中的电化学参数变化;使用白光干涉仪以及扫描电子显微镜分别对钢样的显微组织形貌和磨痕形貌进行了表征,结果表明:随着Cl-浓度的增加,钢样摩擦系数降低,在腐蚀的耦合作用则会加剧材料损失,导致磨痕轮廓截面变宽、磨损量增加、腐蚀电位发生负移,钢样的腐蚀加剧. 其中磨损量由占材料损失量的86.2%降至78.2%. 当钢样处于开路电位时,低盐度模拟海水中磨损机制为磨粒磨损为主伴随腐蚀磨损,高盐度模拟海水中磨损机制为腐蚀磨损和疲劳磨损共存;处于阴极保护电位时,在各种Cl-浓度(0~1.2 mol/L)下的磨损机制都以磨粒磨损为主. 通过对摩擦腐蚀耦合的定量分析,证实了两者相互促进,且在Cl-浓度达到0.6 mol/L时摩擦与腐蚀的协同耦合作用影响最大.

     

    Abstract: Using the UMT-2 multifunctional friction and wear tester to test the reciprocating friction behavior of FH36 marine low-temperature steel plates under open circuit potential and cathodic protection potential with different salinities seawater. Combined with electrochemical workstation to explore the friction corrosion of FH36 steel samples and the change of electrochemical parameters during this process. White light interferometer and scanning electron microscope were used to characterize the microstructure morphology and wear scar morphology of the steel samples. The results showed that with the increase of Cl- concentration, the friction coefficient decreased, but the profile of wear scar and wear amount increase gradually, the open corrosion potential shifted negatively, and the corrosion tendency of the steel sample increased correspondingly. Among them, the amount of wear decreased from 86.2% of the material loss to 78.2%. When the steel sample was at the open circuit potential, the wear mechanism in the low-salinity simulated seawater was abrasive wear, and the wear mechanism in the high-salinity simulated seawater was corrosion wear and fatigue wear; when the steel sample was at the cathodic protection potential, the wear process at various Cl concentrations (0~1.2 mol/L) was mainly abrasive wear. Through the quantitative analysis of the friction corrosion coupling, it was confirmed that the abrasive wear and corrosion wear promoted each other during the tribocorrosion tests of FH36 low alloy carbon steel. The coupling effect had the greatest influence when the Cl concentration reached 0.6 mol/L and the material loss was mainly dominated by abrasive wear followed by corrosion wear at this critical point.

     

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